Basic Copper Carbonate

Specifications

Copper Carbonate Basic	A.R.	C.P.	Electro-plating grade	Technical grad
Assay(as Cu) %	52.5~56.5	52.5~56.5	≥55	≥55
Chlorides(Cl) %	≤0.001	≤0.005	≤0.04	≤0.05
Sulphates(SO4)%	≤0.01	≤0.02	≤0.02	≤0.06
Ammonium salt(NH4)%	≤0.1	≤0.2	≤0.2	——
Iron (Fe)%	≤0.01	≤0.05	≤0.03	≤0.03
Nitrates(NO3)%	≤0.03	≤0.05	≤0.03	——
Acid Insoluble %	≤0.01	≤0.02	≤0.15	≤0.1
Non-precipitate in sulfured hydrogen(As sulphates) %	≤0.75	≤1.0	≤1.0	——
Zinc (Zn)%	——	——	≤0.03	——
Arsenic (As)%	——	——	≤0.01	≤0.005
Lead (Pb)%	——	——	≤0.01	——
Sodium (Na)%	——	——	——	——
Calcium (Ca)%	——	——	——	——
Chromium (Cr）%	——	——	——	≤0.003
Aluminum (Al)%	——	——	——	≤0.01
Cadmium (Cd)%	——	——	——	≤0.001
Copper Carbonate Basic	Export (dry)	Export (wet)	Light super-fine grade
Assay(as Cu) %	≥55	≥46	≥55
Chlorides(Cl) %	≤0.05	≤0.04	≤0.05
Sulphates(SO4)%	≤0.05	≤0.04	≤0.05
Acid Insoluble %	≤0.1	≤0.1	≤0.1
Sodium (Na)%	≤0.3	≤0.25	≤0.3
Calcium (Ca)%	≤0.03	≤0.03	≤0.03
Chromium (Cr) %	≤0.003	≤0.003	≤0.003
Iron (Fe)%	≤0.03	≤0.03	≤0.03
Arsenic (As)%	≤0.01	≤0.005	≤0.005
Lead (Pb)%	≤0.01	≤0.01	≤0.01
Aluminum (Al)%	≤0.01	≤0.01	≤0.01
Cadmium (Cd)%	≤0.001	≤0.001	≤0.001
Zinc (Zn)%	≤0.04	≤0.03	——
Ethanolamine(MEA) Insoluble %	≤0.20	≤0.10	Sieve No.200≥98

Packing& Storage

Packing	25Kg woven bag with double PE liners, closed tightly.
Storage	20℃, 2 years.
Shipping	Room temperature in China; may vary elsewhere

General Information

1.1 Chemical & Physical Properties

Common Names	Cupric carbonate basic \| [μ-[carbonato(2)-κO:κO’]]dihydroxydicopper
Structure
CAS　No.	12069-69-1	Boiling Point (℃)	333.6ºC at 760 mmHg
Molecular Weight	221.116	Melting Point (℃)	200 °C
Appearance	Peacock green fine amorphous powder	Vapor Specific Gravity	N/A
HS Code	2836999000	Flash Point (℃)	169.8ºC
Solubility	Insoluble in water and alcohol. Soluble in acid, ammonia and potassium cyanide solution	Autoignition Temperature (℃)	N/A

1.2 Safety Information

Safety Phrases	S26-S36
RIDADR	UN3288
WGK Germany	2
Packaging Group	III
Hazard Class	6.1

	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use local exhaust or breathing protection.	Fresh air, rest.
Skin	Redness. Burning sensation. Itching.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness. Pain.	Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Nausea. Vomiting.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

1.3 Synthetic Route

1. Copper sulfate method: the baking soda is prepared into a solution with a relative density of 1.05, first added to the reactor, at 50 °C, the refined copper sulfate solution is added under stirring, the reaction temperature is controlled at 70~80 °C, the reaction is precipitated into peacock green as the degree, the pH value is kept at 8, after the reaction is static, sedimentation, washed with 70~80 °C water or ionized water until the washing solution is SO2-4, and then centrifuged and separated, dried to obtain a basic copper carbonate product.
Copper nitrate method. Operation method: electrolytic copper and concentrated nitric acid react to generate copper chamber acid, and then react with the mixture of sodium carbonate and sodium bicarbonate to generate basic copper carbonate, and the precipitation is washed, separated, dehydrated and dried to obtain a finished basic copper carbonate product.

Copper Carbonate Basic