China Nickel Industry

China is one of the largest producers and consumers of nickel in the world. The country has significant nickel resources and plays a crucial role in the global nickel market. Here are some key points about China’s nickel industry:

  1. Production: China has both nickel mines and nickel pig iron (NPI) production facilities. NPI is a low-grade nickel product derived from laterite ores, and China is a major producer of this material. The country also produces refined nickel through smelting and refining processes.
  2. Consumption: China is the world’s largest consumer of nickel due to its vast industrial base and infrastructure development. Nickel is primarily used in stainless steel production, which accounts for a significant portion of China’s nickel consumption. Other applications include batteries, electroplating, and alloy production.
  3. Imports: Despite being a major producer, China still imports a substantial amount of nickel to meet its domestic demand. The country imports both raw materials, such as nickel ores and concentrates, as well as refined nickel products from other countries.
  4. Nickel Ores: China has significant reserves of nickel laterite ores, particularly in regions like Guangxi, Hubei, and Yunnan. These ores are used in the production of NPI. Additionally, China also imports nickel ores from countries like Indonesia, the Philippines, and New Caledonia.
  5. Environmental Regulations: In recent years, China has implemented stricter environmental regulations on its mining and smelting industries, including nickel production. These measures aim to reduce pollution and promote sustainable development. Compliance with environmental standards has led to some closures or suspensions of nickel production facilities in the country.
  6. Electric Vehicle (EV) Industry: China is the world’s largest market for electric vehicles, and the growing EV industry has increased the demand for nickel-containing batteries. Nickel is a vital component in lithium-ion batteries used in electric vehicles, and China’s EV ambitions have contributed to the rising nickel demand.
  7. Nickel Prices: China’s nickel industry, like other commodity sectors, is influenced by global nickel prices. Fluctuations in nickel prices impact production, consumption, and trade patterns within the country.
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Application of Nickel Hydroxide in Batteries

Nickel hydroxide (Ni(OH)2) is commonly used as an active material in rechargeable batteries, particularly in nickel-metal hydride (NiMH) batteries. NiMH batteries have been widely used in various applications, including portable electronics, hybrid vehicles, and renewable energy systems. Here are some key applications of nickel hydroxide in batteries:

  1. Nickel-Metal Hydride (NiMH) Batteries: Nickel hydroxide serves as the positive electrode (cathode) material in NiMH batteries. It undergoes reversible electrochemical reactions during charge and discharge cycles. During charging, nickel hydroxide is oxidized to form nickel oxyhydroxide (NiOOH) and releases hydroxide ions. During discharge, the hydroxide ions are consumed, and nickel hydroxide is reduced back to its original form. This reversible redox reaction allows for repeated charging and discharging cycles, making NiMH batteries rechargeable.
  2. Portable Electronics: NiMH batteries have been widely used in various portable electronic devices, including digital cameras, cordless phones, portable music players, and flashlights. They offer a good balance of energy density, power output, and affordability, making them a popular choice for these applications.
  3. Hybrid and Electric Vehicles: Nickel hydroxide-based NiMH batteries have been used in hybrid vehicles as a part of the energy storage system. They provide a higher energy density compared to traditional lead-acid batteries, allowing for longer electric driving ranges. While newer electric vehicles (EVs) predominantly use lithium-ion batteries, NiMH batteries are still used in some hybrid models.
  4. Renewable Energy Systems: NiMH batteries find applications in renewable energy systems, such as solar power and wind power storage. They can store excess energy generated during peak production and release it during periods of low production or high demand. Their robustness, low self-discharge rates, and relative safety make them suitable for these energy storage applications.

While nickel hydroxide has been widely used in NiMH batteries, its use has declined in recent years due to the emergence of lithium-ion batteries. Lithium-ion batteries offer higher energy density, longer cycle life, and improved performance, which has led to their dominance in many applications. Nonetheless, nickel hydroxide-based NiMH batteries still have a place in certain industries and applications.

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Application of Nickel Oxide in Ceramics

Nickel oxide (NiO) is a versatile compound that finds several applications in ceramics. Here are some common applications of nickel oxide in the field of ceramics:

  1. Coloring Agent: Nickel oxide is often used as a colorant in ceramic glazes and pigments. It imparts various shades of green and brown to ceramic products, depending on the concentration used and the firing conditions. This makes it valuable for creating decorative and artistic effects in pottery, tiles, and other ceramic items.
  2. Opacifier: In ceramic formulations, nickel oxide can act as an opacifying agent, reducing the transparency or translucency of glazes or ceramic bodies. It helps to create opaque or semi-opaque finishes, providing a different aesthetic appearance to the final product.
  3. Thermal Barrier Coatings: Nickel oxide, in combination with other ceramic materials, is utilized in the production of thermal barrier coatings (TBCs). TBCs are used in high-temperature applications, such as gas turbines and aerospace components, to protect underlying materials from extreme heat. Nickel oxide-based TBCs offer excellent thermal insulation properties and can withstand high temperatures.
  4. Solid Oxide Fuel Cells (SOFCs): Nickel oxide is an important component in the manufacturing of solid oxide fuel cells. In SOFCs, it is used as an electrode material, particularly in the anode, due to its high electronic conductivity at elevated temperatures. Nickel oxide-based anodes help in the efficient conversion of fuel to electricity in these fuel cell systems.
  5. Sensors: Nickel oxide is also employed in the production of ceramic sensors. It is used as a sensing material in gas sensors, humidity sensors, and other types of sensing devices. The electrical properties of nickel oxide can be altered based on the presence of certain gases or changes in humidity, allowing it to function as a sensing element.
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What is Nickel Oxide Used For?

Nickel oxide (NiO) has various applications in different fields. Here are some common uses of nickel oxide:

  1. Catalysis: Nickel oxide is widely used as a catalyst in several chemical reactions. It can promote oxidation and reduction reactions and is employed in processes such as hydrogenation, dehydrogenation, and methanation. Additionally, it finds applications in the production of ceramic materials and in the synthesis of various organic compounds.
  2. Batteries: Nickel oxide is a key component in rechargeable nickel-cadmium (NiCd) and nickel-metal hydride (NiMH) batteries. It serves as the positive electrode material (cathode), reacting with metal hydrides or cadmium to store and release electrical energy.
  3. Ceramic Industry: Due to its stability at high temperatures, nickel oxide is utilized in the production of ceramic glazes and pigments. It imparts specific colors, such as black or green, to ceramic products.
  4. Sensors: Nickel oxide is employed in gas sensing devices, particularly in detecting reducing gases like carbon monoxide (CO) and hydrogen (H2). The change in electrical properties of nickel oxide when exposed to these gases enables their detection.
  5. Electrochromic Devices: Nickel oxide thin films are utilized in electrochromic devices, which can change their optical properties (such as light transmission and reflection) in response to an applied electric field. These devices are used in smart windows, rear-view mirrors, and other applications where adjustable light transmission is desired.
  6. Fuel Cells: Nickel oxide is used as a catalyst in solid oxide fuel cells (SOFCs). It promotes the oxidation of hydrogen or hydrocarbons to produce electricity in these high-temperature fuel cell systems.
  7. Glass Industry: In the glass industry, nickel oxide is employed as a colorant to produce green glass, which finds application in decorative glassware, bottles, and architectural glass.
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The Close Relationship between Nickel and Stainless Steel

Stainless steel is often divided into martensitic stainless steel, ferrite stainless steel, austenitic stainless steel, austenitic ferrite duplex stainless steel and precipitated hardened stainless steel. Whether as stainless steel plate or heat-resistant steel plate, austenitic steel plate has the best comprehensive performance. It has sufficient strength, and excellent plasticity. This is one of the reasons why austenitic stainless steel is so widely adopted. Similar to most other metal materials, the tensile strength, yield strength and hardness of austenitic stainless steel increase with decreasing temperature. And plasticity decreases with decreasing temperature. The tensile strength increases uniformly in the range of 15 to 80°C. More importantly, the impact toughness decreases slowly with the decrease of temperature, and there is no brittle transition temperature. So stainless steel at low temperature can maintain enough plasticity and toughness. The heat resistance of stainless steel refers to the oxidation resistance or corrosion resistance of gas medium at high temperature. That is thermal stability. Austenitic stainless steel contains more than 18% chromium, but also contains about 8% nickel and a small amount of molybdenum, titanium, nitrogen and other elements.

Nickel is an important alloying element in austenitic stainless steel. Nickel has great influence on the microstructure and properties of austenitic stainless steel. Its main function is to stabilize austenite and make steel obtain complete austenite structure. This makes the steel get good strength, plasticity, hot and cold workability, cold formability, welding and no magnetic properties. At the same time, nickel can improve the thermodynamic stability of austenitic stainless steel. Compared with the chromium and molybdenum content of ferrite, martensitic and other stainless steel, nickel austenitic stainless steel has better rust resistance and oxidation resistance. And it can improve the stability of the surface film. This also makes the steel have more excellent resistance to reducing media properties.

1. Characteristics of Nickel

  • Physical properties. Nickel is a silver-white metal with magnetic properties and good plasticity. Nickel is a malleable and ferromagnetic metallic element that is highly polished and resistant to corrosion. Dissolved in nitric acid, it appears green. It is used chiefly in alloys (e.g., nickel steel and nickel silver) and as a catalyst (e.g., laney nickel, especially as a catalyst for hydrogenation).
  • Chemical properties: Nickel is insoluble in water, forming a dense oxide film on the surface of the humid air at room temperature, which can prevent the continued oxidation of the main metal. It can dissolve slowly in dilute acid and release hydrogen gas to produce green Ni-divalent ion Ni (strong alkali resistance). Nickel can be burned in pure oxygen, producing a brilliant white glow. Nickel can also be burned in chlorine and fluorine. The oxidizing solution, including nitric acid, does not react. Nickel is a moderate-strength reducing agent. Nickel is slowly corroded by hydrochloric acid, sulfuric acid, organic acid and alkaline solution. Nickel dissolves slowly in dilute nitric acid. Fuming nitric acid can passivate nickel surface and has corrosion resistance. Nickel, like platinum and palladium, can absorb a large amount of hydrogen during passivation. The smaller the particle size is, the greater the absorption will be.

2. Influence of Nickel on Stainless Steel Structure

Nickel is an element that strongly stabilizes austenite and expands the austenitic phase region. In order to obtain a single austenitic structure, the minimum nickel content required for steel containing 0.1% carbon and 18% chromium is about 8%. This is the most famous 18-8 chromium nickel austenitic stainless steel basic fraction. In austenitic stainless steel, with the increase of nickel content, the residual ferrite can be completely eliminated. With the increase of nickel content, the solubility of carbon in austenitic stainless steel will be reduced and the tendency of carbide precipitation will be enhanced.

3. Influence of Nickel on the Properties of Stainless Steel

The influence of nickel on the mechanical properties of austenitic stainless steel, especially chromium-nickel austenitic stainless steel, is mainly determined by the influence of nickel on austenitic stability. In the range of nickel content in steel where martensitic transformation may occur, the strength of steel decreases and the plasticity increases with the increase of nickel content. Chromium-nickel austenite has stable austenitic structure, and its stainless steel toughness (including extremely low temperature toughness) is very good, so it can be used as low temperature steel. This is well known. The toughness of chromium manganese austenitic stainless steel with stable austenitic structure can be further improved by adding nickel. Nickel can also significantly reduce the cold working hardening tendency of austenitic stainless steel. The stability of austenite increases, reduces or even eliminates the martensitic transformation in the cold working process. And the cold working hardening of austenite itself is not obvious. When talking about the influence of cold working hardening tendency of stainless steel, nickel reduces the cold working hardening rate of austenitic stainless steel, and reduces the strength of steel at room temperature and low temperature. It also improves the role of plasticity. This determines that the increase of nickel content is conducive to the cold working formability of austenitic stainless steel. The increase of nickel content can also reduce or eliminate the δ ferrite in 18-8 and 17-14-2 chromium nickel austenitic stainless steel, thus improving its hot working performance. However, the decrease of δ ferrite is detrimental to the weld ability of these steels and increases the tendency to weld hot crack wires. In addition, nickel can significantly improve the hot working properties of chromium-manganese-nickel-nitrogen austenitic stainless steel, thus significantly increasing the yield of steel. In austenitic stainless steel, the addition of nickel and the increase of its content lead to the increase of thermodynamic stability. Therefore, austenitic stainless steel has better rust resistance and oxidation resistance of the medium performance. With the increase of nickel content, the resistance of austenitic stainless steel to reducing medium is further improved. It is worth pointing out that nickel is also the only important element to improve the resistance of austenitic stainless steel to trans-granular stress corrosion in many media. It should also be pointed out that under some conditions of high temperature and high pressure water, the increase of nickel content leads to the increase of the inter-granular stress corrosion sensitivity of steels and alloys. However, this adverse effect can be alleviated or inhibited with the increase of chromium content in steel and alloy. With the increase of nickel content in austenitic stainless steel, the critical carbon content of inter-granular corrosion decreases. That is the sensitivity of the steel to inter-granular corrosion increases. Nickel has no significant effect on the resistance of austenitic stainless steel to spot corrosion and slot corrosion. In addition, nickel can improve the oxidation resistance of austenitic stainless steel at high temperature. This mainly improved the composition of the chromium oxide film with nickel. In general, simple chromium nickel (and chromium manganese nitrogen) austenitic stainless steel is only used under conditions requiring non-rust and oxidation resistant media (such as nitric acid).

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Introduction to Nickel Sulfate

Nickel Sulfate is a fairly good conductor of heat and electricity. It takes on a high polish. Its magnetic properties and chemical activity resemble iron and cobalt. It has properties to form easily a number of alloys. Nickel alloys are used in making coins and heat exchange items like valve.Nickel is combined with many other elements, including chlorine, sulfur, and oxygen, exist.
Nickel Sulfate takes on a high polish. Its magnetic properties and chemical activity resemble iron and cobalt. It has properties to form easily a number of alloys. Nickel alloys are used in making coins and heat exchange items like valve.Nickel Sulfate is mainly used to make stainless steel as a protective and ornamental coating for less corrosion.Most of these nickel compounds dissolve easily in water and have a characteristic green or blue color with no characteristic odor or taste.
JuRui Chemical Co.,Limited is a factory based professional cobalt salt, nickel salt and copper salt series supplier of China with years of exportation experience.We’d like to provide you the best products with good price.

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