Nanjing Liwei Chemical Co., Ltd

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Metastannic Acid: Development, Properties, and Modern Insights

Historical Development

Interest in metastannic acid began in the early 19th century, when chemists experimented with tin compounds for pigment and ceramic uses. Names like Berzelius and Wohler recognized the differences between various forms of tin oxides. Experimenters boiled tin in nitric acid, producing a peculiar white solid with properties unlike regular stannic acid. Early confusion around its composition led to debates in journals, but persistent research, including the work of German chemists, clarified the difference between hydrated tin oxides and defined metastannic acid’s main characteristics. As the years passed, industries drew on these findings to create pigments and develop simple tests for tin, gradually expanding from academic curiosity to a pivotal chemical for manufacturers who wanted stable, insoluble compounds.

Product Overview

Metastannic acid often appears as an amorphous, white, odorless powder with poor solubility in water or acids. Stannic acid suppliers present it for use in laboratories and industry, emphasizing its reactivity with metals and abilities as a retentive filter material. The acid’s complicated physical structure means suppliers batch test each lot for consistency—a nod to its variable hydration levels and the need for accurate formulation. Labeling borrows from common synonyms like “tin(IV) oxide hydrate,” and technical data sheets echo the traditions founded over a hundred years ago, assuring purity and verifying that lifecycles pose low persistent hazard to end-users.

Physical & Chemical Properties

With the formula SnO2·nH2O, metastannic acid combines tin dioxide with water in a ratio that wavers between batches, so chemists never treat it as a fixed hydrate. Its bulky, granular consistency explains why it doesn’t dissolve in boiling water or concentrated acids—the dense polymeric chains simply entangle water molecules. What stands out is its capacity to adsorb substances, like coloring agents and metal ions, which earns it a role in pigment preparation and water purification. The solid keeps stability in both air and light. Despite appearances, it's not a simple crystalline powder but a gelatinous matrix that holds significant moisture, evident from its tendency to clump if left out too long. Only caustic alkalis break it down into soluble stannates, proof of its chemical reluctance, but that suits most applications fine, since it means pigments don’t wash away or leach into soils.

Technical Specifications & Labeling

Quality controllers check tin content through X-ray fluorescence or wet chemistry, looking for at least 60–65% tin by weight on the oxide basis, matching guidelines developed decades ago. Good manufacturing practice means checking loss on drying, as too much water signals incomplete processing, changing the reactivity in downstream uses. Some batches come stamped as “chemically pure” or “technical grade”—stamps that may sound bureaucratic, but practical users know these mean fewer impurities such as chlorides or iron that interfere with catalysts or ceramic glazes. Standard product codes, UN numbers, and hazard labels indicate risks, but metastannic acid rarely shows much threat in normal handling. Documentation focuses on batch history, tin content, moisture level, and absence of heavy metals like lead or arsenic.

Preparation Method

Most plants produce metastannic acid by digesting metallic tin or tin salts in hot concentrated nitric acid, driving out nitrous fumes and forming a thick, insoluble precipitate. Chemists rinse this mass multiple times to remove residue nitrate ions, then dry the cake under moderate heat. Experienced operators watch color and consistency, since over-acidification can trap nitrates, while under-treatment yields incomplete conversion. Laboratories sometimes use tin(IV) chloride as a shortcut, but the same principle applies: destabilize the tin salt, form a hydrated oxide, wash well, and collect the purified gel-like deposit.

Chemical Reactions & Modifications

Metastannic acid acts as an acid rather than a base—no surprise given its composition. It readily forms salts with alkali metals by reacting with solutions such as sodium hydroxide, producing soluble stannates. In combination with transition metals, it works as an ion exchanger, offering up sites for cation absorption. Pigment manufacturers combine it with chromates or other colored metal salts to produce stable, lightfast mineral colors, while electronics firms exploit its insulating properties in specialized glass coatings. Because the acid's structure brings so many hydroxyl groups to the surface, simple heating or mechanical grinding can drive off water or change surface reactivity, opening a path to composites and hybrid materials.

Synonyms & Product Names

Manufacturers and scientists call it metastannic acid, tin(IV) oxide hydrate, metatinic acid, or hydrated stannic oxide, and sometimes just “tin acid.” Catalogs echo these names, though some older labels refer to it as “pyroxylin” or “pyrotin” in historical German texts. Most regulatory bodies recognize CAS Number 12027-70-2 or EC Number 234-847-1 for standardized handling, but end users tend to go by the simple names, reflecting familiarity in research and industrial circles.

Safety & Operational Standards

By tradition and ongoing study, metastannic acid earns a generally low hazard profile, yet responsible users wear gloves and dust masks to cut back on inhalation and skin contact. Granular dust can irritate lungs if mishandled, a point labs never ignore. Large spills need wet cleaning to trap particles, warehouses keep bins sealed, and Safety Data Sheets describe the right fire extinguishing agents and first aid steps for exposure. Environmental releases risk clogging aquatic gills, so disposal always goes through solid waste streams, never poured down drains. Training for new staff covers the main risks: dust, storage, and cold water washing if skin comes into contact.

Application Area

Paints, ceramics, textile finishing, and water purification make up the bulk of metastannic acid’s use. Artists and manufacturers mix it into glazes to control color stability and opacity. Its adsorptive character finds a place in water treatment, pulling out heavy metal contaminants and dyes. Analysts rely on it for sensitive detection of tin, and specialty glass-makers introduce it for durable, transparent coatings. In some cases, catalyst designers look at metastannic acid as a support for precious metals, drawn to the strong interactions between tin oxide surfaces and Noble metals. Academic research points to its ability to function as a selective adsorbent or even as a mediator in electron transfer in emerging electronics fields.

Research & Development

Laboratories dig deeper into metastannic acid’s microstructure using electron microscopy and advanced spectroscopy, linking surface area with chemical activity. Trends show an uptick in exploring doped and hybrid forms, blending in minor metals to create new sensor platforms for gas detection or components for printed electronics. Researchers study the water-holding network within metastannic acid to design advanced membranes, while others push for greener production by recycling tin from industrial byproducts. Investment in R&D includes not just process optimization, but also scaling up manufacturing so the material meets the growing demands in environmental remediation and sustainable chemistry.

Toxicity Research

Toxicologists review data collected from animal studies and workplace monitoring, and the consensus up to now suggests low acute toxicity for metastannic acid. Chronic exposure in poorly ventilated settings can cause mild lung irritation and possible granulomas if dust becomes airborne, but no firm links to carcinogenicity or major organ damage. Regulatory agencies in Europe and the US set occupational exposure limits and require manufacturers to fit labeling to GHS standards, so most risks come down to good hygiene and ventilation. Ongoing studies check for new endpoints, focusing on nanostructured versions, since tiny fragments may act differently inside the body compared to larger aggregates. Community outreach emphasizes the importance of handling all fine powders with respect, even those with a long record of benign use.

Future Prospects

Metastannic acid finds new demand as industries hunt for ways to capture and immobilize toxic ions and as electronics designers look for non-toxic, earth-abundant materials. Sensor technology expects growth, with doping and composite formation pushing properties into ranges suitable for fine chemical monitoring and environmental tracking. Green chemistry, especially circular production methods reusing post-consumer tin, stands to lower both environmental impact and costs. Regulatory developments watch out for any shifts in safety profiles, particularly as the material moves into advanced applications. Through practical innovation, metastannic acid leaves behind its legacy as a pigment and standard lab compound, carving out a niche in energy storage, pollution removal, and next-generation manufacturing. Its story moves forward with every batch tested and every application validated, blending long tradition with urgent modern needs.



What is Metastannic Acid used for?

The Background on Metastannic Acid

Metastannic acid doesn’t grab headlines. Ask someone on the street about it and you’ll probably get a blank stare. The truth is, this white, tasteless powder is a staple in laboratories and industries, though rarely is it the star. In my own experience of working in a college chemistry lab, I saw it tucked away on the shelves, reliable and never running out of use. At its heart, metastannic acid is a stannic acid form that comes from stannic chloride’s reaction with water. Its role in chemistry feels quiet but essential, and its uses are wider than many realize.

Why Industry Relies on Metastannic Acid

In the tin plating and ceramics world, metastannic acid is a familiar friend. Factories depend on it for its powerful stabilizing ability; it helps give the right texture and properties to ceramic glazes. Pottery needs a glaze that won’t crack and will stick properly to the surface, which is harder to achieve than people think. The consistent results that manufacturers get often come down to the chemical workhorses like metastannic acid.

In my talks with someone involved in pigment production, I learned that this acid plays an underrated role in coloring and paint. They needed something that bound pigments tightly to each other, and metastannic acid did the heavy lifting. When it acts as a medium for pigments in paints or inks, the resulting products stand up to fading and weathering better than many alternatives.

Metastannic Acid in Research and Medicine

Research labs use this acid as a solid support for catalysts. I remember a post-grad at my university who stopped his project cold when a shipment was delayed. Without metastannic acid, his process for producing certain organic molecules just fell apart. The acid’s unique surface and structure came through by holding precious metals like platinum, letting scientists run precise chemical reactions. Catalysis research depends on repeatable, reliable platforms for reactions, and that reliability makes a difference between a breakthrough and hours of troubleshooting.

Medical technology also borrows from metastannic acid. Radioactive isotopes get fixed onto the acid for medical imaging. Once a doctor injects this compound, it moves through the body in a predictable way, letting scanners create clear images of the organs. This clarity and predictability guide tricky diagnoses, from damaged kidneys to locating tumors. The consistency here not only supports doctors, but shapes patient outcomes.

Bumps in the Road and the Way Forward

Use of chemicals always raises red flags on safety. Handling tin compounds asks for care—dust inhalation and improper disposal risk health and environmental damage. The challenge isn’t making the compounds work; it’s making sure workers stay protected and the waste stays contained. It reminds me of safety briefings that many seemed to treat as routine, but the importance runs deeper. Nobody wants to see a coworker affected due to a lack of respect for chemical protocols. Companies with a strong safety culture keep incidents down, and they typically invest in extra training and good ventilation.

With pressure growing to find safer and cleaner alternatives, researchers continue to test for new materials that match metastannic acid’s strengths. Some labs push for biologically derived coatings or less toxic stabilizers. From what I’ve seen, tradition dies hard, especially for a compound with a record of reliability. But innovation finds its pace, especially when driven by regulation or a market eager to label products as greener and cleaner.

Looking Beyond the Headlines

Metastannic acid may not seem glamorous, but the work it does quietly shapes everything from fine ceramics to advanced medical scans. In every bottle sitting in a supply room, someone has found a way to lean on its strengths. The full story often lies behind the scenes, with safety practices and ongoing research pushing for better use and improved alternatives. That’s why the everyday compounds matter, even if they keep walking in the background.

What is the chemical formula of Metastannic Acid?

Understanding Metastannic Acid

Metastannic acid goes by the chemical formula H2SnO3. Some chemists know it under the hydrated form H2SnO3·xH2O. Made by treating tin compounds with strong oxidizers like nitric acid, this substance doesn’t fit into tidy, single-molecule models. What comes out in a chemistry lab tends to show up as a white, amorphous solid—a far cry from more familiar crystalline powders most people imagine when thinking about acids.

Why the Formula Catches Attention

H2SnO3 tells a story from the periodic table. Sn means tin. Attach it to oxygen and hydrogen, you enter the world of complex oxides and acids. The formula isn’t just trivia for a chemistry test—real-world labs use this acid when working with tin and testing for its presence. Historians of science still see its name in references back to the 1800s, when researchers first teased apart the tin-oxygen-hydrogen bonds. Metastannic acid behaves stubbornly, resisting dissolution in most acids (other than hydrofluoric), a property that helped 19th-century scientists prove it wasn’t just a regular salt or hydrate, but a new compound altogether.

Applications and Industrial Role

Metastannic acid doesn't pop up in household cabinets or under the kitchen sink. A chemist will find it in analytical chemistry and industrial processes, primarily where a tin source that’s not easily soluble in water is required. Tap into industrial applications and you might see it acting as an intermediate in making tin oxide (SnO2), which works in ceramics, glass, and even in gas sensors. SnO2 shows up in the glaze on tiles, in catalysts, and increasingly in technologies that touch clean air and sensing materials.

Any time high-purity tin compounds are needed, this acid’s unique properties come in handy. While not the star player in large-scale manufacturing, its role as a precursor to other tin compounds has kept it in the toolkit for decades. Experience handling such compounds in college labs shows it’s one of those rare materials people use to explore foundational chemistry—especially redox behavior and metal-acid relationships. It forces students and researchers to think beyond the limits of clear solutions and salt crystals.

Fact-Checking and Safety Considerations

Reports by established sources like the Merck Index and chemistry handbooks back up the chemical formula of metastannic acid. Reliable synthesis and characterization keep it a standard in scientific literature. The acid doesn’t create the health hazards that strong mineral acids do, though it still calls for the usual lab safety measures. Rubber gloves, eye protection, and careful disposal prevent unnecessary accidents, as with any specialized chemical.

Looking Ahead: Modern Use and Research Potential

Scientific research has opened new doors for metastannic acid. Materials science experiments have explored its role in novel electrochemical devices. Environmental chemists continue to examine tin and its oxides in water purification, using metastannic acid as a research tool. Moving beyond its classic applications, its formula—H2SnO3—remains a central thread, linking basic research in inorganic chemistry to applications that touch technology, health, and industry.

How should Metastannic Acid be stored?

Daily Lab Habits Shape Safety

Working with chemicals doesn’t just test your memory for formulas—it calls for habits that protect everyone in the lab. Metastannic acid, with its chalky appearance and unpredictable nature, really brings this point home. A decade ago, I saw carelessness with storage lead to ruined samples and, worse, a hasty evacuation over a spill. Such incidents don’t always make headlines, but they shape how professionals view everyday risks. Personal experience shows that a few practical steps can prevent trouble weeks down the line.

Moisture & Air: The Unseen Threats

Metastannic acid attracts moisture like a sponge on a muggy day. Exposing it to damp air spells out disaster, polluting the product and threatening experiments. Store it in tightly sealed glass containers instead of plastics that flex or degrade. Glass won’t leach substances or react the way cheaper materials sometimes do, making it the gold standard for purity and safety. I once worked in a lab that tried cutting costs with recycled containers—bad call. After repeated contamination issues, we went back to proper jarred seals and never looked back.

Light & Heat: Enemies in Disguise

Direct sunlight isn’t just bad for fading old books on a windowsill—over time, it ruins metastannic acid. UV rays and heat speed up unwanted reactions, sometimes making a whole batch unstable. Dark, cool cabinets away from lab hot spots keep the acid steady. Years ago, a sunbeam creeping past the blinds transformed what should have been a stable powder into a funky mess before our next inspection.

Labeling Isn’t Just Busywork

A simple label saves hours and maybe an emergency call. Forgetting to label metastannic acid can mean a colleague grabs the wrong powder, risking dangerous mixing. Write out full names and date everything by hand; shorthand markings fade or rub off. I’ve seen even experienced chemists double-check when labels are clear. This one habit—the old-school sticky label—costs pennies and saves thousands.

Proper Segregation Saves Money and Nerves

Mixing storage for acids and bases creates a risk that nobody wants to clean up. Separate metastannic acid from reactive chemicals, flammables, and anything else that rests on the “maybe” list from your high school chemistry class. Shelves with raised edges help catch knocked-over containers before disaster hits the floor.

Community Standards Matter

The best labs don’t work in isolation. They follow consensus safety guidelines drawn from shared mistakes and science. Resources from the National Institute for Occupational Safety and Health (NIOSH) and U.S. Occupational Safety and Health Administration (OSHA) don’t just add red tape—they save real lives. I’ve joined peer safety audits that forced our team to rethink lazy habits, and every lab professional should get comfortable with real-time feedback.

Reduce Waste, Prevent Accidents

Storing only what you need sidesteps hoarding and cuts accident risks. If you’ve got a chemical like metastannic acid sitting untouched for years, it’s time to rethink your inventory. Rotate old stock forward and clear out expired containers. Call in a professional for hazardous waste pickup—it keeps your coworkers and local environment safer.

Better Storage, Better Science

Responsible storage links directly to reliable results and staff health. Small changes—airtight containers, vigilant labeling, separation from incompatible substances—make a major difference in the lab. A few extra minutes invested today protect research integrity and, more importantly, the people behind the science.

Is Metastannic Acid hazardous or toxic?

Getting the Facts on Metastannic Acid

Metastannic acid, behind its technical name, plays a minor role in many chemical labs and industries. Most folks will never bump into it outside of a research setting. Built on tin and oxygen, this compound grabs the attention of folks working with ceramics, glass, or as part of some chemical syntheses. Before anyone tunes out, it helps to get a clear handle on whether it brings any serious health or environmental problems.

What Research Shows About Toxicity

If you dig into the scientific literature and safety data, this substance rarely pops up as a top concern for chemists or occupational health experts. The standard Material Safety Data Sheets (MSDS) list classic advice: avoid inhalation, don’t eat or drink it, don’t let it touch your skin for long. This isn’t unusual advice for inorganic compounds, especially those based on metals. Certain tin compounds carry real risks—organotin compounds, for example, are linked to toxic effects in both humans and wildlife. Metastannic acid, though, doesn’t behave like those notorious chemicals.

The available animal studies don’t throw up red flags for cancer, developmental problems, or big long-term risks from low-level exposures. That being said, it’s no vitamin pill. Any fine powder can sit in your airways or lungs if you get careless, and that includes metastannic acid.

Worker Safety and Exposure Concerns

From my own time working in quality control at a ceramics plant, powdered tin compounds managed to sneak everywhere. People who handled them every day were handed dust masks, gloves, and strict rules about using the material under fume hoods. The logic stayed simple—better to avoid breathing any powder than regret it years later. Chronic exposure to metal oxides, even the less notorious ones, can cause irritation or allergies for a small minority. Rinsing off after work and keeping food out of the lab seemed like a small price for peace of mind.

Unlike copper sulfate or lead-based substances, metastannic acid doesn’t leave lasting health stories among lab staff. Reports of major accidents involving the substance are scarce. Most trouble comes from careless handling—spills that lead to temporary skin or eye irritation. It doesn’t build up in living tissue like mercury or certain pesticides do.

Environmental Impact Matters, Too

Environmentally, metastannic acid doesn’t earn inclusion on worldwide restricted chemical lists. Tin in environmental samples rarely causes as much alarm as heavy metals like cadmium or arsenic. Still, a slow build-up of tin oxides in soil or water over decades could shift things, especially as more exotic materials find industrial uses.

Reducing Risks and Smart Handling

Sticking with common-sense precautions pays off for businesses and researchers alike. Dust control through proper ventilation and respirators limits risks almost to zero. Quick cleanup of spills and safely storing bags and jars full of powder keep unexpected contact minimal. For the few who develop allergies or sensitivities, job rotation or tighter personal protection can keep careers running smoothly.

The bottom line: Metastannic acid doesn’t deserve top billing as a hazard, but respect for workplace risks shouldn’t fade. Understanding what each chemical does, checking monitoring data, and keeping safety gear up-to-date prove their worth every day. That practical approach keeps jobs and personal health steady for years to come.

What are the physical properties of Metastannic Acid?

What Sets Metastannic Acid Apart Physically

Metastannic acid comes up in chemistry labs as a white, powdery substance with some peculiar features. Most people haven’t heard of it unless they’ve done hands-on work around tin chemistry. This compound, made when strong acids react with tin salts or by treating tin dioxide (SnO2) with acids, doesn’t look that interesting at a glance. Still, there’s more going on at the microscopic level. Unlike well-ordered crystals you get from table salt or sugar, this stuff behaves like a loose, spongy network. That’s because it’s what chemists call “amorphous”—there’s no clear repeating pattern in its structure, just a tangled mess of atoms. That lack of structure changes how it handles water, heat, and even other chemicals.

Handling Water and Moisture

Take water, for starters. Regular stannic acid barely draws in moisture, but metastannic acid grabs onto it. This is what makes metastannic acid a hydrous powder—water molecules stick pretty firmly to its atomic tangle. In the lab, I watched this stuff puff up slightly in humid air. You notice it when you try to dry metastannic acid for weighing: It clings to water and that can mess up your results if you’re trying to be precise. That stickiness comes from the open, gel-like nature of the amorphous mass. Granular tin compounds just don’t trap water the same way.

Texture and Appearance

Physically, the first thing you notice is the texture. Metastannic acid is not gritty or sandy. It feels pasty, sometimes gummy, especially if it’s been exposed to air for any length of time. Old laboratory guides talk about scooping it out and finding the powder has almost caked together. That happens because absorbed water makes it clump. Compare this to a crystalline compound, where every bit shakes free and packs down cleanly. Here, metastannic acid’s structure makes for a fluffier experience and a messier bench.

Solubility and Chemical Behavior

The water absorption ties into another important feature: insolubility in water and most common solvents. This can be traced to the random, cross-linked web that water can’t easily pry apart. Even strong acids, except concentrated ones like hydrochloric that can break down the structure outright, slide off metastannic acid without much impact. That’s a reason it’s used to separate tin from mixtures in certain types of chemical analysis—a trait I had to take advantage of more than once while working up old ore samples. If you’re handling the solid, it rarely dissolves away on you, which gives you more control in separation procedures.

Thermal Properties

Metastannic acid’s loose structure holds up until real heat arrives. At normal temperatures, you don’t notice much. Once heated to a few hundred degrees, things start to change. It dries out as trapped water escapes, producing an almost crackling effect if you watch closely. Heating even further, it converts into tin dioxide, a far more compact and stable solid. This heat-driven transformation matters for anyone processing tin or recycling scrap—those steps all depend on heating metastannic acid until it becomes something else, and that underlying flexibility starts with its physical makeup.

Handling in Everyday Use

Safety-wise, the powdery texture means it can go airborne. I’ve seen colleagues get a whiff of irritation in the nose when working carelessly. Proper handling and dust control should be standard whenever metastannic acid is on the bench. It isn’t a material that poses great risk of poisoning but, like all fine powders, it deserves a healthy respect. For anyone working around it, gloves and dust masks make sure that its sticky, hydrous nature doesn’t cause trouble, even in a tightly run chemical operation.

Metastannic Acid
Metastannic Acid
Names
Preferred IUPAC name hydroxyoxostannane
Other names Stannic acid
Meta-stannic acid
Hydrated tin(IV) oxide
Amorphous tin dioxide
Tin acid
Pronunciation /ˌmɛtəˈstænɪk ˈæsɪd/
Identifiers
CAS Number 12037-38-2
Beilstein Reference 476291
ChEBI CHEBI:30418
ChEMBL CHEMBL1201811
ChemSpider 143470
DrugBank DB13708
ECHA InfoCard 18c7e913-cd4e-44b1-b952-41cacb7a418c
EC Number 231-588-9
Gmelin Reference 83774
KEGG C18798
MeSH D008756
PubChem CID 26017
RTECS number WH6650000
UNII 61R7GJ20L9
UN number 3262
CompTox Dashboard (EPA) Metastannic Acid: "DTXSID3046721
Properties
Chemical formula H2SnO3
Molar mass 315.716 g/mol
Appearance White amorphous powder
Odor Odorless
Density 4.11 g/cm³
Solubility in water Insoluble
log P -2.30
Vapor pressure Negligible
Acidity (pKa) ~1.7
Basicity (pKb) 5.0
Magnetic susceptibility (χ) -85.0·10⁻⁶ cm³/mol
Refractive index (nD) 1.87
Dipole moment 0 D
Thermochemistry
Std molar entropy (S⦵298) 85.0 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -907 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) –644 kJ·mol⁻¹
Pharmacology
ATC code V09CA02
Hazards
Main hazards May cause irritation to the eyes, skin, and respiratory tract.
GHS labelling GHS02, GHS07
Pictograms GHS05
Signal word Warning
Hazard statements H301: Toxic if swallowed.
Precautionary statements P264, P280, P301+P312, P305+P351+P338, P330, P337+P313, P501
NFPA 704 (fire diamond) 2-0-0
Lethal dose or concentration LD50 (oral, rat): > 5,000 mg/kg
LD50 (median dose) Oral rat LD50: > 2000 mg/kg
NIOSH SN1225000
PEL (Permissible) Not established
REL (Recommended) REL: 0.1 mg Sn/m³
Related compounds
Related compounds Stannic oxide
Stannous chloride