Cobaltous oxide has carried weight in industry ever since early chemists found cobalt in the 18th century. European glassmakers and potters recognized the vibrant blue coloring, even if the pure compound’s role remained unclear. Over time, the compound took on distinct importance beyond art. The late 19th century marked progress in isolating, producing, and understanding this oxide. Metallurgists and chemists pressed on research to support the needs of expanding electricity, alloy manufacture, and ceramics. Laboratories honed reliable production, and by century’s end, cobaltous oxide secured steady demand in heavy and fine industries. It has become a textbook example of how a material can switch from a coloring agent to a backbone of several high-tech fields.
Cobaltous oxide, sometimes referred to in older labs as cobalt(II) oxide or simply as CoO, usually comes as a fine olive-green powder or sometimes as large grayish lumps. Many producers target high purity standards for chemical uses, while some blends tolerate minor iron or copper as byproducts from raw ore processing. Every bag or drum tells a story: demanding customers in battery, pigment, and catalyst sectors expect tightly controlled synthesis and an assurance of traceability to accepted mining or recycling standards. Companies selling cobaltous oxide must put transparency in sourcing and batch testing first to stand up to regulatory scrutiny and ethical concerns around cobalt mining.
The oxide stands out for its high melting point near 1935°C and an insolubility in water. In air, the material stays stable at room temperature, but on heating it shifts to higher cobalt oxides, taking on hues from greenish to deep black. Cobaltous oxide shows antiferromagnetic behavior below its Néel point, which grabbed attention in physics research circles years before the Internet. In acid, the powder dissolves and forms cobaltous salts used in both basic and specialty chemistry. Its density sits above 6 g/cm³, which can be a hurdle for some mixing and blending operations and calls for careful dust control.
Industry buyers demand a clear breakdown: percent cobalt content, purity, grain size, and absence of regulated contaminants like arsenic. Typical chemical-grade cobaltous oxide contains above 72% cobalt and traces of sodium, calcium, iron, or magnesium kept below prescribed thresholds. Material safety data sheets often walk through physical characters, shelf life, lot numbers, and hazard statements. Clear labeling with Globally Harmonized System (GHS) pictograms signals toxicity concerns and shipping codes. As cobalt is traded globally, paperwork also tracks country of origin, batch results, and lead, mercury, or cadmium levels to keep exports within REACH and RoHS regulations. Buyers expect immediate access to test certificates and safe handling guides for worker training.
The traditional route takes cobalt metal or recovered cobalt salts and roasts them with air, sometimes as a two-step process. Heating cobalt carbonate or cobalt nitrate will drive off gases and leave behind the green oxide. Direct oxidation of cobalt powder at carefully controlled temperatures helps tune the resulting particle structure and reactivity. Some industries, especially battery makers, prefer coprecipitation approaches where dissolved cobalt ions get converted in alkaline solutions and finally calcined in a kiln. Each recipe affects not just chemistry but cost, labor safety demands, and sometimes waste or byproduct management.
Cobaltous oxide plays well in both reduction and oxidation settings. It reduces to metallic cobalt under hydrogen and oxidizes to cobalt(III) oxide if given enough air and heat. Reacting with mineral acids forms cobalt(II) salts, showing up in water treatment, pigment production, and analytical chemistry. Glassmakers often tweak the oxide’s reactivity to produce custom blues and turquoises. Battery researchers push further, using chemical or hydrothermal methods to morph basic CoO into layered composites that store and shuttle lithium ions. Catalyst producers react the oxide with other transition metals to fine-tune catalytic cycles for Fischer-Tropsch or hydrodesulfurization plants. These modifications aren’t just academic; battery life and fuel efficiency depend on getting the recipe right.
You might spot it as cobalt monoxide, CoO, or simply cobalt(II) oxide, depending on the catalog or regulatory listing. Some vintage text calls it asbestos blue due to past uses in glazing. Commercial packaging usually highlights cobalt powder oxide or includes batch-specific codes, since applications from electrodes to ceramics set strict parameters. In international supply chains, accurate chemical names and synonyms help dodge confusion around shipping, customs, and legal records. Scientists and workers trust standardized naming to catch potential incompatibilities—so a name is never just a name here.
Safety keeps coming up with cobaltous oxide. Chronic exposure carries risks for respiratory, reproductive, and cardiovascular health. Workers must suit up in proper gear: masks, gloves, tight-fitting goggles. Storage away from strong acids, food, and flammables reduces accidental mixing and contamination. Factories install dust extraction and monitor airborne particles in real time. Accident protocols include shower stations and fresh-air rotation for affected personnel. Hazard labels show up clearly: the oxide enters the lungs quickly and authorities want mitigation against leaks, spills, or accidental swallowing. Waste cobalt scrap and residues get handled under hazardous waste codes and trusted EHS teams supervise regular risk assessments alongside medical screenings. Customers also look for written assurance of standards—from OSHA exposure limits to local fire codes.
Cobaltous oxide finds a place in the hands of battery makers hunting for reliable lithium-ion or nickel-cadmium performance. Apple and EV factories track its source and chemistry down to the kilogram. Ceramicists see it as a bright, tough colorant, while glass manufacturers lean on its hue and fire resistance. Petroleum refineries buy tons each month as a catalyst ingredient for sulfur removal; the life of their catalyst changes dramatically with subtle tweaks in oxide sourcing. Paints, glazes, magnetic data storage—each of these rests on stable supply and chemical predictability. Some labs deploy the compound in animal nutrition, carefully measuring doses to dodge toxicity while supplying needed micronutrients. Shifts in tech—like sodium-ion batteries or new types of supercapacitors—push researchers to expand the oxide’s reach.
Research groups see cobaltous oxide as a platform for new materials. Modifying crystals, shifting oxidation states, and blending with dopants have turned labs into playgrounds for energy storage progress. Scientific publications in 2023 alone describe tuning particle sizes for better catalytic reactivity or optimizing crystal structure for extended charge cycles in high-energy batteries. Funding from both public agencies and private groups has brought cross-border collaboration: European labs hunt alternatives to minimize environmental load, while Asian institutes develop chemical recycling to reduce primary mining. The need for sustainable cobalt loops, combined with new safety data and real-time workplace monitoring, brings hope of practical improvements rather than just theoretical gains.
Toxicologists stay focused on the oxide’s entry pathways and dose limits. Studies show how inhaled dust leads to lung inflammation or fibrosis. Regulatory agencies keep pushing for lower occupational exposure limits after seeing links between long-term workplace exposure and elevated cancer or reproductive risk. Water solubility and dustiness go under the microscope, since they affect both immediate accidents and chronic low-level absorption into the body. New animal research quantifies acute thresholds, but translating those numbers into practical rules for factories and labs remains a bigger challenge. Industry groups work alongside medical researchers and trade unions to close data gaps and publish robust guidelines, knowing that public pressure grows as global supply chains open up.
The world’s push for electric transport, green energy, and waste reduction puts a spotlight on cobaltous oxide. Markets demand traceable, responsibly sourced material. Recycling technologies draw more investment, since battery-grade cobaltous oxide from spent electronics supports both environmental and supply chain resilience. Work’s underway to improve substitute chemistries with more abundant metals, yet nothing else brings quite the same suite of properties—melting point, color, catalytic action. The expectation is continued growth in smart grid storage, smaller electronics, and hydrogen-production catalysts. That growth brings new ethical and technical questions: how to cut risk for workers in mines and factories, keep product streams clean, and return value to communities supplying the raw cobalt. Real-world improvements will draw as much from community input as from tweaks in chemistry and process engineering.
Cobaltous oxide doesn’t get as much spotlight as iron or copper, but in the world of colors it’s a heavy hitter. The striking blues seen on tiles, pottery, or prized antique vases? Those often come from compounds built with cobaltous oxide. Walk past a mural or cup your hands around a hand-painted mug and there’s a decent chance cobaltous oxide played a part in making those blues stand out.
I’ve seen how a tiny bit of this stuff, often just grams per batch, turns clear glass a deep blue or gives pottery an almost hypnotic sheen. Artisans and industrial workers alike rely on its reliability—throw in the right amount and your batch won’t turn a murky gray or washed-out azure. There’s real trust in that sort of predictability. It’s not just tradition either. Big glass manufacturers still lean on cobaltous oxide for blue glass bottles, dinnerware, and stained-glass for windows and lamps.
Away from artists’ studios, cobaltous oxide holds a spot in modern technology. Most smartphones, laptops, and electric cars use batteries built from lithium-cobalt blends. The oxide strengthens performance and keeps the charge flowing. There’s no colorful magic here—instead, cobaltous oxide sits unseen, crucial for storing energy in small spaces.
This connection becomes clearer whenever a battery recall or shortage hits the headlines. The global hunger for rechargeable tech drives up demand, leading to real concerns over mining, trade, and the working conditions in places where cobalt is pulled from the earth. Here’s where things get tricky: the world wants faster, longer-lasting gadgets, but digging up more cobalt often comes with a human cost. According to Amnesty International, unsafe mines in places like the Democratic Republic of Congo supply more than half of the world’s cobalt, with children exposed to unsafe conditions. It’s a cycle nobody seems eager to break but too many accept in exchange for better tech.
Finding a better way forward calls for pressure from every angle. Consumers asking where battery materials come from, companies sourcing more responsibly, and engineers chasing alternative chemistries—all of this matters. Researchers at major universities are testing new ways to reclaim cobalt from old batteries, cutting down on the need for newly mined oxide. Recyclers can now pull cobalt and other metals from tired-out batteries, turning waste into useful products again.
In ceramics, some studios even seek out recycled or ethically produced cobalt, echoing the broader movement toward sustainable art and production. Choosing certain suppliers and asking questions about supply chains starts to shift the tide. These small acts, along with larger policy changes and new technology, spark real hope for improvement.
It’s easy to overlook the legacy hiding in a jar of blue pigment or the screen lighting up right now. Cobaltous oxide, in its different forms, brings brilliance and power to old art and new devices alike. Its story isn’t just about science or industry—it's about what we expect from the things we use, and the push for balance between innovation and responsibility.
Cobaltous oxide, a deep olive-green powder, crops up in industries from ceramics to batteries. Folks who work around it likely know its color and texture better than what risks lurk in the dust. Having spent time in factories where heavy metals shape every shift, I learned early that familiarity with a material doesn’t make it safe. Cobaltous oxide deserves careful attention before anyone shrugs off the warning signs.
Breathing fine dust seems like the norm on a tile shop floor or during battery production, but cobalt compounds aren’t just another particle. Studies in occupational health journals show that inhaling dust laced with cobalt oxide irritates lungs and inflames airways. NIOSH, the research arm for worker safety, sets a limit at just 0.05 mg/m³ for airborne cobalt compounds, including the oxide form. That low number speaks volumes. Their scientists have seen how lungs exposed for weeks or months can develop scarring, and in serious cases, workers show signs of a condition called “hard metal lung disease.”
Most people think about their lungs first, but swallowing or absorbing cobaltous oxide through the skin deserves respect too, especially where safety procedures slide. A 2016 review in Environmental Health Perspectives saw links between chronic cobalt exposure and heart issues. Batteries and pigments mean possible skin contact, and repeated absorption can build up cobalt inside the body, affecting the blood and heart over time. The International Agency for Research on Cancer finds enough evidence in animal studies to consider cobaltous oxide possibly carcinogenic. That word unsettles most people, and it should.
Communities near cobalt mining and processing sites deal with environmental exposures, not just those clocking in for a shift. Kids in areas near smelters, for example, pick up exposure even in schools or playing outdoors. Blood tests sometimes show cobalt levels above what public health folks consider acceptable. People don’t choose what floats in on the breeze, so companies and regulators share a duty to keep emissions in check.
The solution isn’t found in avoidance—industries using cobaltous oxide support thousands of jobs—so focus shifts to practical steps. In my experience, decent ventilation, wetting down dusty work surfaces, and using personal respirators lower daily dangers. Workers stay healthiest when trained to spot dust hazards and push for clean-up, not cut corners. Regular health checks catch problems early. Labeling, safety briefings, and open reporting channels help too. Outside factory walls, public reporting of emissions holds companies accountable and arms local residents with information.
Even basic actions make a difference. Wearing gloves, keeping eating areas separate, and washing hands before lunch cuts down what gets into the body. Simple? Maybe, but effective if folks make it routine. Companies that regularly upgrade safety gear and respond to employee concerns keep risk lower and morale higher. These steps set a real-world example: take cobaltous oxide seriously, protect the people who work with it, and keep communities informed—nobody needs to gamble with their health on a job site.
Cobaltous oxide has always drawn interest in both chemical research and real-world industries. The simple formula for cobaltous oxide is CoO. Here, cobalt takes a valence of +2, and oxygen balances the charge with -2. Together, they form a compound that features more often in daily life and major industries than most folks realize.
Cobaltous oxide often ends up in places that shape our surroundings. In ceramics, potters use it to put a sky-blue color on tiles and pottery. Glassmakers mix in CoO to get beautiful blue hues without affecting the quality or strength. Batteries would look and run very differently without cobalt oxides. Rechargeable lithium-ion batteries in phones and electric cars get their durability and energy density in part from CoO chemistry. The compound’s role in catalysts cannot go unnoticed either—it helps chemicals turn into fuels and plastics during industrial production.
Working with something like cobaltous oxide comes with responsibility. Inhaling its dust or getting too much skin contact can produce health risks, including respiratory irritation and possible long-term issues. Companies running big kilns or battery plants need trained workers and solid protocols, not just a long list of warnings taped to a wall. I once watched a workplace safety review at a facility making pigments from CoO, and the staff there put real effort into handling, storage, and protective gear. It goes to show: people, not policies alone, shape safety outcomes.
It all starts with how we mine cobalt. Large-scale extraction, mostly from Africa, brings challenges—including unsafe labor practices and environmental strain. Every stage, from digging the ore to producing CoO, leaves a mark on workers and communities. Improving transparency in supply chains and working with groups like the Responsible Cobalt Initiative brings a chance to drive positive change. When battery makers or pigment suppliers publish independent audits or allow NGO visits, everyone down the line benefits.
The need for alternatives also feels urgent. As batteries grow in demand, research teams search for materials that work as well as cobaltous oxide but avoid ethical and cost pressures. Some startups already test chemistries using iron or nickel blends. Still, CoO has a proven record that won’t vanish overnight. Labs ought to keep studying recycling methods too; reusing cobalt from old batteries means less mining, fewer emissions, and a smaller global footprint.
Understanding the chemical formula is just the start of grasping this compound’s role in technologies and everyday items. Every person who goes beyond rote memorization and digs into the story behind a chemical like CoO gains tools to make choices as consumers, neighbors, or professionals. Real expertise grows from connecting science with local impacts, ethics, and safety. The chemical industry changes rapidly, but core principles like accurate knowledge, transparency, and respect for people will always matter most.
Cobaltous oxide may sound like just another recyclable hazard, but anyone who’s worked near a barrel of the stuff knows it asks for more respect than the label suggests. Its uses stretch from pigments in ceramics to battery tech, but storage errors turn routine workdays into chaos quickly. Whether someone’s running a university lab or managing a plant floor, the basics of handling this compound look remarkably similar.
Humidity loves to invite trouble to the party. Moisture can make cobaltous oxide clump, turn dusty surfaces sticky, and start chemical changes nobody wants. Folks often stash it in dry rooms with desiccants close by, keeping everything crisp and manageable. Temperature swings mess with stability, so a steady, cool environment works best.
I once saw a maintenance closet in a paint factory where the air conditioner failed for a week. Drums of cobalt compounds caked up, making later mixing uneven and cleanup trickier. After that summer, the warehouse got better cooling and a big, bold humidity gauge right by the loading dock. That fixed the headaches and protected both people and materials inside.
Putting cobaltous oxide in flimsy bags or cracked jars lets powder leak or soak moisture right up. Use heavy-duty containers with tight lids—think steel drums, not cardboard boxes. Keep them clearly labeled, warning signs out front and chemical names big enough for anyone to read at a glance.
Label mix-ups happen faster than you’d think. Once I caught a shipment headed out the door with “zinc oxide” tags, just because two interns swapped lids in a rush. Printing big, color-coded stickers cut down on mistakes and brought everyone’s stress levels way down.
Some chemicals don’t play well together, and cobaltous oxide falls in that camp. Never stack it by acids or organics. Accidental mixing or a knocked-over shelf can kick off reactions, sometimes pumping out toxic fumes. Store it well apart, keeping aisles clear and making sure staff know not to park “just for a minute” next to the wrong materials.
Building a habit of daily checks pays off. One shift leader told me his crew walks storage shelves each afternoon, looking for dents, spills, or misplaced bins. Those five minutes keep small mistakes from blowing up into major emergencies—or worse, sending someone to the hospital.
No one should breathe easy near loose cobalt dust. Inhaling the stuff may damage lungs and, over long periods, could help cancer take root. Always store it where extraction fans work and personal masks hang close to the door. Sweeping powder spills with a broom only spreads the hazard, so use vacuums with proper filters.
People are the first line of defense against accidents. Good storage means little if workers don’t know what they’re handling. Routine safety talks, clear signage, and quick access to data sheets make everyone safer. It isn’t enough to say “use gloves”—show the burns that happen without them. When the crew sees the evidence and understands the risks, the careful habits stick.
Safe storage of cobaltous oxide doesn’t require high-end tech or endless procedures. It calls for consistency, common sense, and people who look out for each other. A dry room, tough barrels, honest training, and a dose of vigilance offer real protection for both workers and the wider world outside the storeroom.
Cobaltous oxide, often found as a dark gray to olive-green powder or sometimes as greenish-black crystals, strikes a curious first impression for anyone who’s actually handled it. Its color alone sets it apart from other metallic oxides lined up in any lab or industrial environment. You scoop this stuff out, it leaves a faint dusty mark on your hands and work surfaces. There’s nothing subtle about this material; it makes itself known right away.
The stuff feels gritty, not slick or glassy. Try rubbing it between your fingers––wear gloves––and you’ll feel its fine, powdery presence, evidence of its crystalline makeup. Cobaltous oxide doesn’t just sit there. It packs density, measuring at about 6.45 grams per cubic centimeter. Years of working with metal oxides showed me how important it is to know what you’re dealing with in the shop or lab. A high-density powder needs careful handling and precise storage, or else you find it caking up in containers, almost as though it's trying to become one solid chunk over time.
Heat brings out more character in this oxide. Its melting point shoots up to about 1,933°C. In a practical sense, most workshop furnaces can’t even touch that temperature. This is not something you accidentally burn off or decompose in day-to-day processes. That heat resistance gives it staying power wherever loads of heat come into play: ceramic glazes, catalysts, even magnet production. Over the years, I’ve noticed how that unyielding nature helps create durable products that last.
Cobaltous oxide shrugs off water. Toss it into a beaker and you’ll see it just sink without mingling, almost like tiny stones in a pond. That lack of solubility tells a lot about where it fits—and where it doesn’t. You won’t find it running into water supplies or bubbling away in simple solutions. Cobaltous oxide does dissolve in acids, though, which opens the door for chemical synthesis and recovery operations. I spent years preparing mixtures for pigments and ceramics; knowing what dissolves (and what doesn’t) saved both money and time.
This oxide’s deep green and black hues find a home in glassmaking and ceramics. Add just a pinch, and you’ll see vibrant blue or green results, which caught my attention early on—small moves can shift color in big ways. What’s less obvious is its magnetic behavior. While not a full-blown magnet, it responds just enough to warrant respect around sensitive electronic gear. Spend time in a shop and you learn to check what you’re handling before bringing it near delicate sensors.
Safety can’t go overlooked. Cobaltous oxide in powder form becomes airborne quickly, ready for inhalation if you rush through cleanup or pour without care. Long exposures build up risks, which I learned over years working side by side with seasoned old-timers in pigment shops. Decent ventilation, gloves, and proper dust masks keep those risks at bay.
Working with cobaltous oxide means respecting its strengths and limits. Changes in how we handle such powders—better dust management, improved tracking of exposure, and investment in safer containers—have already made a difference in health and workflow. Stronger standards for heat-resistant equipment and handling procedures reduce downtime and improve yields. Matching physical properties with specific applications shows respect both for the tools and the people using them. Real progress starts not with theory, but with every small step taken toward smarter, safer practices.


| Names | |
| Preferred IUPAC name | cobalt(II) oxide |
| Other names |
Cobalt(II) oxide
Cobalt monoxide Cobaltous oxide |
| Pronunciation | /koʊˈbæl.təs ˈɑk.saɪd/ |
| Identifiers | |
| CAS Number | 1307-96-6 |
| Beilstein Reference | 3587066 |
| ChEBI | CHEBI:60042 |
| ChEMBL | CHEMBL1201600 |
| ChemSpider | 14129 |
| DrugBank | DB11354 |
| ECHA InfoCard | 100.013.481 |
| EC Number | 215-154-6 |
| Gmelin Reference | Gmelin Reference: "Co 33 |
| KEGG | C18567 |
| MeSH | D003059 |
| PubChem CID | 14803 |
| RTECS number | GF8750000 |
| UNII | 1KX876B1Z7 |
| UN number | UN3288 |
| CompTox Dashboard (EPA) | DTXSID7020182 |
| Properties | |
| Chemical formula | CoO |
| Molar mass | 74.9326 g/mol |
| Appearance | Fine olive-green powder |
| Odor | Odorless |
| Density | 6.44 g/cm³ |
| Solubility in water | Insoluble |
| log P | -4.1 |
| Vapor pressure | Negligible |
| Basicity (pKb) | 14.43 |
| Magnetic susceptibility (χ) | +3.3e-3 |
| Refractive index (nD) | 1.92 |
| Dipole moment | 0 D |
| Thermochemistry | |
| Std molar entropy (S⦵298) | 43.0 J/(mol·K) |
| Std enthalpy of formation (ΔfH⦵298) | -237 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | -237 kJ·mol⁻¹ |
| Pharmacology | |
| ATC code | V07BB02 |
| Hazards | |
| Main hazards | Toxic if swallowed, in contact with skin or if inhaled; suspected of causing genetic defects; may cause cancer; may cause damage to organs through prolonged or repeated exposure; very toxic to aquatic life with long lasting effects. |
| GHS labelling | GHS02, GHS06, GHS08 |
| Pictograms | GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H302, H317, H319, H332, H334, H335, H341, H350, H360Fd, H410 |
| Precautionary statements | P201, P202, P260, P264, P270, P272, P273, P280, P302+P352, P304+P340, P308+P313, P314, P321, P332+P313, P362+P364, P405, P501 |
| NFPA 704 (fire diamond) | 2-2-0 |
| Lethal dose or concentration | LD50 oral rat 427 mg/kg |
| LD50 (median dose) | LD50 (median dose): Oral rat LD50 = 424 mg/kg |
| NIOSH | N0387 |
| PEL (Permissible) | 0.1 mg/m3 |
| REL (Recommended) | 10 mg/m3 |
| IDLH (Immediate danger) | 40 mg Co/m3 |
| Related compounds | |
| Related compounds |
Cobalt(III) oxide
Cobalt(II) chloride Cobalt(II) sulfate |